jacketed metering pump for molten sulfur
I have experience with metering molten sulfur and would like to up grade
my pump to something jacketed. I found a 40K usd$ unit which is kind of
expensive for a pump that meters .1-1.5 liter per minute and is not
fully jacketed.
So anybody out there that has experience with metering small quantities of molten sulfur?
anybody know of any companies that offer some nice jacketed metering pumps?
We had similar issues with pumping molten iodine (MP=115C)..
Most of
the pumps (including ceramic piston metering pumps with heat tracing,
PTFE diaphragm pumps in a "hot box" thermostatically controlled to 130
C--I can give you references if you are interested) would end up either
leaking at the seals or freezing.
One idea that we came across
but were never fully able to implement (project ended) was having a feed
tank and metering high temp (130C), pressurized liquid H2O into the
tank. Exactly the same amount of I2 (or sulfur in your case) would be
displaced into the process, assuming that there was no vapor left in the
tank. This takes some design work (obviously) to make sure that there
is adequate pressure relief in case the sulfur solidifies, etc., but it
should be doable.
Possible holes that need to be investigated:
1) Make sure that the densities are significantly different so that you don't get an emulsion of the phases
2)
I think that the equilibrium lies toward elemental sulfur and water,
but make sure that you won't form H2SO3 or other compounds in
significant quantities (sulfur chem definitely seems complicated)
3)
Obviously, this could cause trouble if trace amounts of water will be an
issue. We were desperate to find a way to get the I2 flowing, though,
and this was one of the few promising, possibly repeatable ways within
our budget that we could find.
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